Potassium dichromate \( (K_2Cr_2O_7) \) is prepared from chromite ore \( (FeCr_2O_4) \) through the following
steps: 1. Roasting with Sodium Carbonate: \[ FeCr_2O_4 + 4Na_2CO_3 + 7O_2 \rightarrow 2Na_2CrO_4 + 2Fe_2O_3 + 4CO_2 \]
2. Conversion to Dichromate: \[ 2Na_2CrO_4 + H_2SO_4 \rightarrow Na_2Cr_2O_7 + Na_2SO_4 + H_2O \]
3. Formation of Potassium Dichromate: \[ Na_2Cr_2O_7 + 2KCl \rightarrow K_2Cr_2O_7 + 2NaCl \]
List-I (Type of Crystalline Solid) | List-II (Example) |
(A) Ionic | (III) Sodium Chloride, NaCl |
(B) Covalent | (IV) Diamond, C |
(C) Molecular | (I) Methane, CH4 |
(D) Metallic | (II) Copper, Cu |
Mention the number of unpaired electrons and geometry of the following complexes:
(i) \([NiCl_4]^{2-}\)
(ii) \([Ni(CN)_4]^{2-}\)
Convert the following:
(a) Ethanenitrile into ethanal.
(b) Cyclohexane into adipic acid.