Write the IUPAC name of the following complex: \([\text{Co}(\text{NH}_3)_5(\text{CO}_3)]\text{Cl}\).
The IUPAC name of the complex \([\text{Co}(\text{NH}_3)_5(\text{CO}_3)]\text{Cl}\) is Pentaamminecarbonato cobalt(III) chloride.
Explanation:
- "Pentaammine" refers to the five ammonia (\(\text{NH}_3\)) ligands.
- "Carbonato" refers to the carbonate (\(\text{CO}_3\)) ligand.
- "Cobalt(III)" indicates that cobalt is in the +3 oxidation state.
- "Chloride" is the anion that balances the charge of the complex.
The correct IUPAC name of \([ \text{Pt}(\text{NH}_3)_2\text{Cl}_2 ]^{2+} \) is:
What type of isomerism is shown by the complex \([\text{Co(NH}_3)_6][\text{Cr(CN)}_6]\)?
The given coordination compound \([\text{Co(NH}_3)_6][\text{Cr(CN)}_6]\) exhibits ionization isomerism.
**Explanation:** Ionization isomerism arises when two complexes have the same molecular formula but yield different ions in solution. In this case, the cationic complex \([\text{Co(NH}_3)_6]^{3+}\) and the anionic complex \([\text{Cr(CN)}_6]^{3-}\) could interchange their ligands under different conditions, leading to a different complex with distinct properties.
(a) State the following:
(i) Kohlrausch law of independent migration of ions
A solution of glucose (molar mass = 180 g mol\(^{-1}\)) in water has a boiling point of 100.20°C. Calculate the freezing point of the same solution. Molal constants for water \(K_f\) and \(K_b\) are 1.86 K kg mol\(^{-1}\) and 0.512 K kg mol\(^{-1}\) respectively.
Write the reactions involved when D-glucose is treated with the following reagents: (a) HCN (b) Br\(_2\) water
Identify A and B in each of the following reaction sequence:
(a) \[ CH_3CH_2Cl \xrightarrow{NaCN} A \xrightarrow{H_2/Ni} B \]
(b) \[ C_6H_5NH_2 \xrightarrow{NaNO_2/HCl} A \xrightarrow{C_6H_5NH_2} B \]
Would you expect benzaldehyde to be more reactive or less reactive in nucleophilic addition reactions than propanal? Justify your answer.