(i) Longest chain contains 7 carbons including the carbonyl carbon; the C=O is at C-2.
\[
\boxed{\text{Heptan-2-one}}
\] (ii) Parent chain includes the \(-\mathrm{CHO}\) group \(\Rightarrow\) hexanal; substituents: bromo at C-4 and methyl at C-2.
\[
\boxed{\text{4-Bromo-2-methylhexanal}}
\]
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