Write down the products of ozonolysis of 1,2-dimethylbenzene (o-xylene). How does the result support Kekulé structure for benzene?
Solution and Explanation
O-xylene has two resonance structures:
All three products, i.e., methyl glyoxal, 1, 2-dimethylglyoxal, and glyoxal are obtained from two Kekule structures. Since all three products cannot be obtained from any one of the two structures, this proves that o-xylene is a resonance hybrid of two Kekule structures (I and II).
Top Questions on Alkenes
Arrange the following alkenes in the decreasing order of stability:
Choose the correct answer from the options given below:
- As compared with chlorocyclohexane, which of the following statements correctly apply to chlorobenzene?
The magnitude of negative charge is more on chlorine atom.
The C--Cl bond has partial double bond character.
C--Cl bond is less polar.
C--Cl bond is longer due to repulsion between delocalised electrons of the aromatic ring and lone pairs of electrons of chlorine.
The C--Cl bond is formed using \(sp^2\) hybridised orbital of carbon.
Choose the correct answer from the options given below: The reactions which cannot be applied to prepare an alkene by elimination, are
Choose the correct answer from the options given below:- An optically active alkene having molecular formula C$_8$H$_{16}$ gives acetone as one of the products on ozonolysis. The structure of the alkene is
- What is the major product of the reaction of an alkene with bromine water?
Questions Asked in CBSE Class XI exam
- Balance the following redox reactions by ion-electron method:
(a)MnO4- (aq) + I - (aq) → MnO2(s) + I2(s) (in basic medium)
(b) MnO4- (aq) + SO2(g) → Mn2+(aq) +HSO4- (aq) (in acidic solution)
(c) H2O2(aq)+Fe2+(aq) → Fe3+ (aq) + H2O (l) (in acidic solution)
(d) Cr2O72-+ SO2(g) → Cr3+ (aq) +SO42- (aq) (in acidic solution)- CBSE Class XI
- Oxidation Number
- Write the resonance structures for SO3 , NO2 and NO3-
- CBSE Class XI
- Kossel-Lewis Approach to Chemical Bonding
- At 700 K, equilibrium constant for the reaction:
\(H_2 (g) + I_2 (g) ⇋ 2HI (g)\)
is 54.8. If 0.5 mol L–1 of HI(g) is present at equilibrium at 700 K, what are the concentration of H2(g) and I2(g) assuming that we initially started with HI(g) and allowed it to reach equilibrium at 700 K?- CBSE Class XI
- Law Of Chemical Equilibrium And Equilibrium Constant
- Find the mean deviation about the mean for the data 4, 7, 8, 9, 10, 12, 13, 17.
- CBSE Class XI
- Statistics
Find the mean deviation about the mean for the data 38, 70, 48, 40, 42, 55, 63, 46, 54, 44.
- CBSE Class XI
- Statistics
Concepts Used:
Alkenes
Alkenes
In organic chemistry, an alkene is a hydrocarbon containing a carbon-carbon double bond.[1]
Alkene is often used as synonym of olefin, that is, any hydrocarbon containing one or more double bonds.
Read More: Ozonolysis
IUPAC Nomenclature of Alkenes
- An alkene or cycloalkene is indicated by the suffix (ending) ene.
- For the root name, the longest chain must include both carbon atoms of the double bond.
- The root chain must be numbered beginning at the end closest to a double bond carbon atom. If the double bond is in the chain's centre, the nearest substituent rule is used to determine where the numbering begins.
- If the compound contains more than one double bond, it is named with a diene, triene, or equivalent prefix indicating the number of double bonds, and each double bond is assigned a locator number.
Read More: Unsaturated Hydrocarbon