Concept: The process is based on the principle of Osmosis. Osmosis is the movement of solvent molecules through a semi-permeable membrane from a region of lower solute concentration to a region of higher solute concentration. For medical injections: Isotonic Solutions: Have the same osmotic pressure as blood ($0.9 %$ w/v $NaCl$).
Hypotonic Solutions: Lower concentration than blood; causes cells to swell and burst (hemolysis).
Hypertonic Solutions: Higher concentration than blood; causes cells to shrink (plasmolysis).
Step 1: Matching Osmotic Pressure.Human blood cells have an osmotic pressure equivalent to a $0.9\%$ (mass/volume) sodium chloride solution, commonly known as normal saline. When medicine is mixed with this saline, the resulting solution remains isotonic with the fluid inside the red blood cells.
Step 2: Preventing Cell Damage. If pure water (hypotonic) were injected, water would enter the red blood cells by osmosis, causing them to swell and potentially burst. Conversely, if a highly concentrated solution (hypertonic) were injected, water would leave the cells, causing them to shrivel. Mixing with saline ensures the cells maintain their normal shape and function.
(i) State Henry’s Law. Give two applications of it.
(ii) Draw the vapour pressure-mole fraction curve for a non-ideal solution having positive deviation, if A and B are the two volatile components.
(i)[Ni(CN)₄]²⁻ and [Ni(CO)(_4)] have different structures, but do not differ in their magnetic behaviour. Explain.
(ii) Write the formula of Tetraamineaquachloridocobalt(III)chloride.
Give reasons for the following:
(i) Zn, Cd and Hg are not considered transition elements.
(ii) Transition metals form complex compounds.
(iii) Sc(3+) is colourless, but Ti(3+) is coloured.