To determine which oxide is the most acidic, we look at the oxides of metals and non-metals. Oxides of non-metals (like Cl\(_2\)O\(_7\)) are generally acidic, while oxides of metals tend to be basic.
- Na\(_2\)O and CaO are basic oxides of metals.
- Al\(_2\)O\(_3\) is amphoteric, meaning it can act as either an acid or a base depending on the conditions.
- Cl\(_2\)O\(_7\) is an acidic oxide and is the strongest acid among the options. It reacts vigorously with water to form acids.
Thus, Cl\(_2\)O\(_7\) is the most acidic oxide.