Which one of the following is incorrect?
- Boron halides are all monomeric while those of Al are dimeric.
- Boron halides and aluminium halides exist as monomeric halides.
- Boron halides and aluminium halides are Lewis acids.
- $B_2O_3$ alone is acidic while $Al_2O_3$ is amphoteric.
The Correct Option is B
Solution and Explanation
Since the boron atom is not surrounded by an octet of electrons, boron halides like BF3 or BCl3 are electron-deficient compounds. They thus have a propensity to operate as potent Lewis acids by taking electrons from several Lewis bases to produce persistent acid-base adducts, serving as catalysts for numerous significant chemical processes.
The bond angle of boron halides, which have a planar structure and a sp2 hybridization, is 120°. The experimentally discovered BX bond lengths, however, are shorter than the values predicted from the halogens' and boron's covalent single bond radii.
In addition to the Lewis acid-base reaction and the most common compounds featuring covalent bonds between a non-metal and a halogen, boron halides are subject to a variety of other reactions. Through hydrolysis processes, these substances react vehemently with water to produce boric acid and hydrogen halide. The broad response below can serve as a representation of this.
Top Questions on p -Block Elements
- $\textbf{Choose the correct statements about the hydrides of group 15 elements.}$
A. The stability of the hydrides decreases in the order \(\text{NH}_3 > \text{PH}_3 > \text{AsH}_3 > \text{SbH}_3 > \text{BiH}_3\)
B. The reducing ability of the hydrides increases in the order \(\text{NH}_3 < \text{PH}_3 < \text{AsH}_3 < \text{SbH}_3 < \text{BiH}_3\)
C. Among the hydrides, \(\text{NH}_3\) is a strong reducing agent while \(\text{BiH}_3\) is a mild reducing agent.
D. The basicity of the hydrides increases in the order \(\text{NH}_3 < \text{PH}_3 < \text{AsH}_3 < \text{SbH}_3 < \text{BiH}_3\)
Choose the most appropriate from the option given below:- JEE Main - 2024
- Chemistry
- p -Block Elements
- $\textbf{Reduction potential of ions are given below:}$
\[ \begin{array}{ccc} \text{ClO}_4^- & \text{IO}_4^- & \text{BrO}_4^- \\ E^\circ = 1.19 \, \text{V} & E^\circ = 1.65 \, \text{V} & E^\circ = 1.74 \, \text{V} \\ \end{array} \]
The correct order of their oxidising power is:- JEE Main - 2024
- Chemistry
- p -Block Elements
- Identify the correct statements about p-block elements and their compounds.
(A) Non metals have higher electronegativity than metals.
(B) Non metals have lower ionisation enthalpy than metals.
(C) Compounds formed between highly reactive nonmetals and highly reactive metals are generally ionic.
(D) The non-metal oxides are generally basic in nature.
(E) The metal oxides are generally acidic or neutral in nature.- JEE Main - 2024
- Chemistry
- p -Block Elements
- In which of the following species, the ratio of s-electrons to p-electrons is the same?
- TS EAMCET - 2024
- Chemistry
- p -Block Elements
The number of oxygen atoms present in chemical formula of fuming sulphuric acid is _______.
- JEE Main - 2024
- Chemistry
- p -Block Elements
Concepts Used:
P-Block Elements
- P block elements are those in which the last electron enters any of the three p-orbitals of their respective shells. Since a p-subshell has three degenerate p-orbitals each of which can accommodate two electrons, therefore in all there are six groups of p-block elements.
- P block elements are shiny and usually a good conductor of electricity and heat as they have a tendency to lose an electron. You will find some amazing properties of elements in a P-block element like gallium. It’s a metal that can melt in the palm of your hand. Silicon is also one of the most important metalloids of the p-block group as it is an important component of glass.
P block elements consist of:
- Group 13 Elements: Boron family
- Group 14 Elements: Carbon family
- Group 15 Elements: Nitrogen family
- Group 16 Elements: Oxygen family
- Group 17 Elements: Fluorine family
- Group 18 Elements: Neon family