Question:

Which of the following statements is INCORRECT for pair of elements $Zr - Hf$ ?

Updated On: May 15, 2024
  • Both possess same number of valence electrons
  • Both have identical atomic sizes
  • Both have almost identical ionic radii
  • Both of these belong to same period of periodic table
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The Correct Option is D

Solution and Explanation

The statement (D), "Both of these belong to same period of periodic table" is incorrect statement. The correct statement is, "Zr belongs to the fifth period and Hf belongs to the sixth period".
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Concepts Used:

D and F Block Elements

The d-block elements are placed in groups 3-12 and F-block elements with 4f and 5f orbital filled progressively. The general electronic configuration of d block elements and f- block elements are (n-1) d 1-10 ns 1-2 and (n-2) f 1-14 (n-1) d1 ns2 respectively. They are commonly known as transition elements because they exhibit multiple oxidation states because of the d-d transition which is possible by the availability of vacant d orbitals in these elements. 

They have variable Oxidation States as well as are good catalysts because they provide a large surface area for the absorption of reaction. They show variable oxidation states to form intermediate with reactants easily. They are mostly lanthanoids and show lanthanoid contraction. Since differentiating electrons enter in an anti-penultimate f subshell. Therefore, these elements are also called inner transition elements.

Read More: The d and f block elements