Step 1: Classification of Hydrides
- Electron-deficient hydrides:
\( B_2H_6 \) (Diborane) lacks enough electrons for bonding, making it electron-deficient.
- Electron-precise hydrides:
\( NH_3 \) is not electron-precise because it has a lone pair.
- Electron-rich hydrides:
\( H_2O \) has lone pairs and is electron-rich.
Thus, the correct matches are \( B_2H_6 \) and \( H_2O \).