Step 1 (Meaning of "available").
"Available" means present, ready for use, or obtainable.
Step 2 (Forming antonyms with prefixes).
Adding the prefix "un-" to a word often creates its opposite meaning.
"Un" + "available" = "unavailable", meaning "not available".
Step 3 (Check other options).
"An-", "in-", and "im-" are valid negative prefixes in some words, but not with "available".
\[
{\text{Un (Option (b)}}
\]