Question:

Which of the following orders of acid strength is correct: 

Updated On: May 5, 2024
  • RCOOH > ROH > HOH > HC ≡ CH
  • RCOOH > HOH > ROH > HC ≡ CH
  • RCOOH > HOH > HC ≡ CH > ROH
  • RCOOH > HC ≡ CH > HOH > ROH
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The Correct Option is B

Solution and Explanation

Here's the rationale behind this order: 
1. Carboxylic acids (RCOOH) are strong acids because they can donate a proton (H+) readily due to the presence of the carboxyl group (COOH). They have a dissociable hydrogen ion (H+), making them stronger acids than the other compounds listed. 
2. Water (HOH) is also a strong acid but not as strong as carboxylic acids. Water can act as an acid by donating a proton (H+) to another molecule or ion, but it is weaker than carboxylic acids in this regard. 
3. Alcohols (ROH) are weaker acids than both carboxylic acids and water. While they can donate a proton, it's less likely to occur compared to carboxylic acids and water. 
4. Alkynes (HC ≡ CH) are the weakest acids among the listed compounds. They are not acidic under normal conditions and do not readily donate protons. 

So, the correct order is (B): RCOOH > HOH > ROH > HC ≡ CH.

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Concepts Used:

Alcohols, Phenols, and Ethers - Chemical Reactions

The reaction of alcohols:

  1. Reaction with Metal
  2. Reaction with Halides
  3. Reaction with HNO3
  4. Reaction with Carboxylic Acid (Esterification)
  5. Dehydration of Alcohol
  6. Haloform Reaction

The reaction of phenols:

  1. Formation of Ester
  2. Hydrogenation
  3. Oxidation of Quinones
  4. Electrophilic Substitution
  5. Halogenation

The reaction of ethers:

  1. Contact with Air
  2. Halogenation of Ether
  3. Electrophilic Substitution Reaction

Read More: Alcohols, Phenols, and Ethers