Step 1: Recall the energy ordering of atomic orbitals. Typically, the energy of orbitals increases with the principal quantum number \(n\), but due to the penetration and shielding effects, some orbitals like \(4s\) are lower in energy than \(3d\).
Step 2: Identify the incorrect order. The correct energy order should be \(4d>5s\), making option (4) incorrect because it states \(4d<5s\).
Match the following: