Calcium carbonate (CaCO\(_3\)) is a common compound found in many minerals and natural materials. It forms a major component of limestone, chalk, and marble.
Step 1: Understanding the Composition of Each Option
- Calcspar (Calcite): A crystalline form of calcium carbonate (CaCO\(_3\)).
- Witherite: Composed of barium carbonate (BaCO\(_3\)), not calcium carbonate.
- Marl: A mixture of clay and calcium carbonate, making it rich in CaCO\(_3\).
- Chalk: A soft, porous form of calcium carbonate (CaCO\(_3\)).
Step 2: Evaluating the Options
- Option (A) - Incorrect: Calcspar (Calcite) is composed of CaCO\(_3\).
- Option (B) - Correct: Witherite contains BaCO\(_3\) instead of CaCO\(_3\).
- Option (C) - Incorrect: Marl contains a high proportion of calcium carbonate.
- Option (D) - Incorrect: Chalk is composed of calcium carbonate.
Step 3: Conclusion
Since Witherite is composed of barium carbonate (BaCO\(_3\)) instead of calcium carbonate (CaCO\(_3\)), the correct answer is option (B).