Iron exhibits different allotropes based on temperature, affecting its crystal structure and properties.
Step 1: Understanding the Allotropic Forms of Iron
- \( \alpha \)-Iron (Ferrite): Stable at room temperature, BCC structure.
- \( \gamma \)-Iron (Austenite): Stable between 912°C and 1394°C, FCC structure.
- \( \delta \)-Iron: Stable between 1394°C and 1538°C, BCC structure.
Step 2: Evaluating the Options
- Option (A) - Incorrect: \( \alpha \)-Iron (Ferrite) is an allotropic form of iron.
- Option (B) - Correct: \( \rho \) is not an allotropic form of iron.
- Option (C) - Incorrect: \( \gamma \)-Iron (Austenite) is a stable form of iron at high temperatures.
- Option (D) - Incorrect: \( \theta \) represents iron carbide (Fe\(_3\)C), which is a compound, not an allotrope.
Step 3: Conclusion
Since \( \rho \) is not an allotropic form of iron, the correct answer is option (B).