Step 1: Define emulsifier.
An emulsifier is a substance that helps in the formation of an emulsion, a mixture of two immiscible liquids like oil and water. It stabilizes the mixture by reducing the surface tension between the two liquids.
Step 2: Analyze the options.
- Soap (Option A) is an emulsifier because it contains both hydrophobic and hydrophilic parts, allowing it to form emulsions between oil and water.
- Oil (Option B) is not an emulsifier, as it is part of the mixture but does not help in stabilizing the emulsion.
- NaCl (Option C) is a salt and does not have emulsifying properties.
- Water (Option D) is a solvent and does not act as an emulsifier.
Step 3: Apply to the options.
The correct answer is (A) Soap.
Final Answer:
\[
\boxed{\text{Soap}}
\]