Step 1: Approaches in nanomaterial synthesis.
- Top-down: Start with bulk material and break it into smaller nanosized particles.
- Bottom-up: Build up nanostructures atom by atom or molecule by molecule. Step 2: Classification of options.
- Chemical vapour deposition: bottom-up.
- Physical vapour deposition: bottom-up.
- Sol-gel process: bottom-up.
- Ball milling: mechanical grinding of bulk → nanosized particles (top-down).
Final Answer:
\[
\boxed{\text{Ball Milling}}
\]