The \( K_b \) value represents the basicity constant, which indicates the strength of a base in water.
1. Step 1: Understand the \( K_b \) value.
- CHCl$_3$: Chloroform is a weak base.
- CCl$_4$: Carbon tetrachloride is essentially a non-basic compound, as it does not act as a base.
- CH$_3$COOH: Acetic acid is a weak acid and does not have a \( K_b \) value because it's not a base.
- NH$_3$: Ammonia is a weak base, and its \( K_b \) value is relatively higher than chloroform or acetic acid.
Thus, NH$_3$ has the highest \( K_b \) value compared to the other options.