Step 1: Understand the structure of chlorophyll.
Chlorophyll is the pigment responsible for the green color in plants and is crucial for photosynthesis. It contains a porphyrin ring with a central metal ion that plays a key role in its function.
Step 2: Review the options.
- Iron is the metal ion found at the center of the porphyrin ring in chlorophyll, which allows chlorophyll to capture light energy.
- Manganese is important in photosynthesis, but not at the center of the chlorophyll molecule.
- Copper is not present at the center of chlorophyll, though it is essential for other enzymatic functions.
- Magnesium is not at the center of chlorophyll's porphyrin ring but is instead a key element in other biological processes.
Step 3: Conclude.
Iron is present at the center of the porphyrin ring in chlorophyll, making option (A) the correct answer.
Final Answer:
\[
\boxed{\text{Iron}}
\]