Question:

Which of the following complex has square planar structure?

Updated On: Aug 27, 2023
  • $\left[ Ni ( CN )_{4}\right]^{2-}$
  • $Ni ( CO )_{4}$
  • $\left[ Zn \left( NH _{3}\right)_{4}\right]^{2+}$
  • $\left[ NiCl _{4}\right]^{2-}$
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The Correct Option is D

Solution and Explanation

$Ni^{2+}(d^{8}) $:
$[Ni(CN)_{4}]^{2-}$ :
$\therefore d s p^{2}$ hybridisation and square planer structure
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Concepts Used:

Coordination Compounds

A coordination compound holds a central metal atom or ion surrounded by various oppositely charged ions or neutral molecules. These molecules or ions are re-bonded to the metal atom or ion by a coordinate bond.

Coordination entity:

A coordination entity composes of a central metal atom or ion bonded to a fixed number of ions or molecules.

Ligands:

A molecule, ion, or group which is bonded to the metal atom or ion in a complex or coordination compound by a coordinate bond is commonly called a ligand. It may be either neutral, positively, or negatively charged.