Question:

Which of the d d -orbital is used in sp3d sp^3d hybridisation?

Updated On: Jun 14, 2022
  • dxy d_{xy}
  • dx2y2 d_{x^2-y^2}
  • dz2 d_{z^2}
  • dyz d_{yz}
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The Correct Option is C

Solution and Explanation

The hybridisation of one ss, one dd and three pp-orbitals on a central atom gives rise to five sp3dsp^3d orbitals, three equatorial and two axial. This hybridisation uses one dz2d_z^2, one ss and all three of the pp orbitals and shape of the molecule becomes trigonal bipyramidal.
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Concepts Used:

Chemical Bonding and Molecular Structure

Such a group of atoms is called a molecule. Obviously, there must be some force that holds these constituent atoms together in the molecules. The attractive force which holds various constituents (atoms, ions, etc.) together in different chemical species is called a chemical bond.

Types of Chemical Bonds:

There are 4 types of chemical bonds which are formed by atoms or molecules to yield compounds. 

  • Ionic Bonds - Ionic bonding is a type of chemical bonding which involves a transfer of electrons from one atom or molecule to another.
  • Covalent Bonds - Compounds that contain carbon commonly exhibit this type of chemical bonding. 
  • Hydrogen Bonds -  It is a type of polar covalent bonding between oxygen and hydrogen wherein the hydrogen develops a partial positive charge
  • Polar Bonds - In Polar Covalent chemical bonding, electrons are shared unequally since the more electronegative atom pulls the electron pair closer to itself and away from the less electronegative atom.

Factors Affecting Bond Enthalpy in Chemical Bonding:

  • Size of the Atom
  • Multiplicity of Bonds
  • Number of Lone Pair of Electrons Present
  • Bond Angle