Question:

The $ EAN $ value $ y \left[Ti\left(\sigma-C_{6}H_{5}\right)_{2}\left(\pi-C_{5}H_{5}\right)_{2}\right]^{0} $ is

Updated On: Nov 6, 2023
  • $ 32 $
  • $ 33 $
  • $ 34 $
  • $ 35 $
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The Correct Option is C

Solution and Explanation

$EAN$ = Atomic number of central atom
- (oxidation state + electron gained by ligand)
Atomic number of $Ti = 22$
Contribution by $\left(\sigma-C_{6}H_{5}\right)=1e^{-}$
Contribution by $(\pi -C_{5}H_{5})=5e^{-}$
$\therefore EAN =22-0+(1\times 2)+(2\times 5)$
$y=34$
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Questions Asked in AMUEEE exam

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Concepts Used:

Coordination Compounds

A coordination compound holds a central metal atom or ion surrounded by various oppositely charged ions or neutral molecules. These molecules or ions are re-bonded to the metal atom or ion by a coordinate bond.

Coordination entity:

A coordination entity composes of a central metal atom or ion bonded to a fixed number of ions or molecules.

Ligands:

A molecule, ion, or group which is bonded to the metal atom or ion in a complex or coordination compound by a coordinate bond is commonly called a ligand. It may be either neutral, positively, or negatively charged.