Step 1: Understanding the Greenhouse effect.
The greenhouse effect refers to the process where certain gases in Earth's atmosphere trap heat, contributing to global warming.
Step 2: Main contributors.
The primary gas responsible for the greenhouse effect is Carbon Dioxide (\(CO_2\)), along with other gases like methane (\(CH_4\)) and water vapor. However, CO2 is considered the most significant due to its high concentration and long-term effects.
Step 3: Conclusion.
Hence, the correct answer is \(CO_2\) as the main contributor to the Greenhouse effect.