The ability to form dihalides depends on the oxidation state and the bonding capabilities of the element. In the 3d transition series:
- Scandium (Sc) forms ScCl\(_3\) (a trihalide), not dihalides.
- Titanium (Ti) can form TiCl\(_2\) (dihalide) in the +2 oxidation state.
- Manganese (Mn) typically forms MnCl\(_2\) in the +2 state, but due to its high oxidation states, it can also form other halides, but dihalides are not common for Mn.
- Iron (Fe) can form FeCl\(_2\) (dihalide) but is more commonly found in higher oxidation states like FeCl\(_3\).
Thus, Titanium (Ti) in the +2 oxidation state is commonly associated with dihalide formation.