What will be the partial pressure of $He$ and $ O_{2} $ respectively, if $200\,mL$ of $He$ at $0.66 \,atm$ and $400 \,mL$ of $ O_{2} $ at $0.52 \,atm$ pressure are mixed in $400 \,mL$ vessel at $ 20^{\circ}C $ ?
Total pressure,
$p =\frac{\text { milliequiv. of } He +\text { milliequiv. } \text { of } O _{2}}{\text { total volume }}$$=\frac{200 \times 0.66+400 \times 0.52}{400}$$=\frac{132+208}{400} $$=\frac{340}{400}=0.85$
Partial pressure of $ He =\frac{\text { milliequiv of } He }{\text { total milliequiv }} \times p$$=\frac{132}{340} \times 0.85 $$=0.33 \,atm $
Similarly, partial pressure of $ O _{2} =\frac{208}{340} \times 0.85 $$=0.52 \,atm $