Volatility is the tendency of a substance to vaporize. Separation of liquid mixtures based on their relative volatilities involves the conversion of a more volatile component into vapor, followed by its condensation.
Distillation is the process specifically designed to exploit this property. It works as follows:
- The mixture is heated.
- The more volatile component (lower boiling point) vaporizes first.
- The vapor is then condensed and collected separately.
This technique is widely used in petroleum refining, alcohol purification, and chemical separation.
Now examining the other options:
Filtration: Used for separating solids from liquids or gases — does not depend on volatility.
Extraction: Used to separate components based on solubility differences.
Adsorption: Relies on adhesion of molecules to a surface — not based on volatility.
Thus, distillation is the correct and most appropriate method for separating liquids based on volatility.