Volatility is the tendency of a substance to vaporize. Separation of liquid mixtures based on their relative volatilities involves the conversion of a more volatile component into vapor, followed by its condensation. Distillation is the process specifically designed to exploit this property. It works as follows:
- The mixture is heated.
- The more volatile component (lower boiling point) vaporizes first.
- The vapor is then condensed and collected separately.
This technique is widely used in petroleum refining, alcohol purification, and chemical separation.
Now examining the other options: Filtration: Used for separating solids from liquids or gases — does not depend on volatility. Extraction: Used to separate components based on solubility differences. Adsorption: Relies on adhesion of molecules to a surface — not based on volatility.
Thus, distillation is the correct and most appropriate method for separating liquids based on volatility.