What is the total number of sigma bonds found in the following compound?
\[ \text{CH}_3\text{CH} = \text{C} = \text{CH} - \text{C} \equiv \text{C} - \text{H} \]
To determine the number of sigma bonds, we need to count the sigma bonds in each bond in the given structure:
The given compound is: \[ {CH}_3{CH} = {C} = {CH} - {C} \equiv {C} - {H} \] 1. Sigma bonds in single bonds:
- Each C-H bond is a single bond, and there are 4 C-H bonds (1 from each methyl group and 1 from the terminal CH group) contributing 4 sigma bonds.
- Each C-C bond in the structure is a single bond (sigma bond), and there are 3 C-C bonds, contributing 3 sigma bonds.
2. Sigma bonds in double bonds:
- Each double bond consists of 1 sigma bond and 1 pi bond. There are 2 double bonds in the compound (C=C), contributing 2 sigma bonds.
3. Sigma bonds in triple bonds:
- Each triple bond consists of 1 sigma bond and 2 pi bonds. There is 1 triple bond (C≡C) contributing 1 sigma bond.
Now, adding all the sigma bonds together:
- 4 sigma bonds from C-H bonds,
- 3 sigma bonds from C-C single bonds,
- 2 sigma bonds from C=C double bonds,
- 1 sigma bond from C≡C triple bond.
Thus, the total number of sigma bonds is: \[ 4 + 3 + 2 + 1 = 11 \] Thus, the correct answer is option (B), 11.
In the Carius method of estimation of halogen, 0.4g of an organic compound gave 0.188g of AgBr. What is the percentage of bromine in the organic compound? (The atomic mass of Ag = 108 g mol\(^{-1}\) & Br = 80 g mol\(^{-1}\))
For the reaction:
\[ 2A + B \rightarrow 2C + D \]
The following kinetic data were obtained for three different experiments performed at the same temperature:
\[ \begin{array}{|c|c|c|c|} \hline \text{Experiment} & [A]_0 \, (\text{M}) & [B]_0 \, (\text{M}) & \text{Initial rate} \, (\text{M/s}) \\ \hline I & 0.10 & 0.10 & 0.10 \\ II & 0.20 & 0.10 & 0.40 \\ III & 0.20 & 0.20 & 0.40 \\ \hline \end{array} \]
The total order and order in [B] for the reaction are respectively: