To find the height \( h \) at which the acceleration due to gravity is \( \frac{1}{4} \) of its surface value \( g \), we use the formula for gravitational acceleration at height \( h \) above the Earth:
\[
g_h = g \left(\frac{R_e}{R_e + h}\right)^2
\]
Where:
- \( g_h \) is the gravitational acceleration at height \( h \),
- \( R_e \) is the radius of the Earth.
Given that \( g_h = \frac{g}{4} \), we substitute this into the equation:
\[
\frac{g}{4} = g \left(\frac{R_e}{R_e + h}\right)^2
\]
Now, we cancel \( g \) from both sides and simplify:
\[
\frac{1}{4} = \left(\frac{R_e}{R_e + h}\right)^2
\]
Taking the square root of both sides:
\[
\frac{1}{2} = \frac{R_e}{R_e + h}
\]
Now, cross-multiply to solve for \( h \):
\[
R_e = 2(R_e + h)
\]
\[
R_e = 2R_e + 2h
\]
\[
2h = R_e
\]
\[
h = \frac{R_e}{2} = 3200 \, {km}
\]
Thus, the height where the acceleration due to gravity is \( \frac{1}{4} \) of its surface value is \( \boxed{3200 \, {km}} \).