Question:
What is the heat of solution of sodium chloride from following data?
Hydration energy of $Na^+ = - 389.4\, kJ\, mol^{-1}$
Hydration energy of $Cl^- = - 382.3\, kJ\, mol^{-1}$
Lattice energy of $NaCl = - 776 \,kJ \,mol^{-1}$
What is the heat of solution of sodium chloride from following data?
Hydration energy of $Na^+ = - 389.4\, kJ\, mol^{-1}$
Hydration energy of $Cl^- = - 382.3\, kJ\, mol^{-1}$
Lattice energy of $NaCl = - 776 \,kJ \,mol^{-1}$
Updated On: Jul 7, 2022
- $+ 8.6\, kJ\, mol^{-1}$
- $+ 4.3\, kJ\, mol^{-1}$
- $- 4.3\, kJ\, mol^{-1}$
- $- 8.6\, kJ\, mol^{-1}$
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The Correct Option is B
Solution and Explanation
Hydration energy of $NaCl = - 389.4 - 382.3$
$= -771.7\, kJ \,mol^{-1}$
$?H_{sol}. =$ Hydration energy - Lattice energy
$= - 771.7 - (-776) = + 4.3 \,kJ \,mol^{-1}$
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Concepts Used:
Group 1 Elements
Group one of alkali metals is s-block elements with just one electron in their s-orbital. They are are alkali metals. They are named so because of the alkaline nature of the hydroxides and oxides.
Alkali metals are characterized by one s-electron in the valence shell of their atoms.
Alkali metals have a corresponding [Noble gas] ns1 electronic configuration. They occupy the first column of the periodic table. Alkali elements are:
- Lithium(Li)
- Sodium(Na)
- Potassium (K)
- Rubidium (Ru)
- Cesium (Cs)
- Francium (Fr)
They have occupied successive periods from first to seven. Francium is a radioactive element with very low half-life.
Electronic Configuration:
- Alkali metals have one electron in their valence shell.
- The electronic configuration is given by ns1. For example, the electronic configuration of lithium is given by 1ns1 2ns1.
- They tend to lose the outer shell electron to form cations with charge +1 (monovalent ions).
This makes them the most electropositive elements and due to the same reason, they are not found in the pure state.