The pH of a solution is defined as the negative logarithm (base 10) of the concentration of hydrogen ions in the solution:
\[
\text{pH} = -\log[\text{H}^+]
\]
If the pH is 4, we can calculate the concentration of hydrogen ions:
\[
[\text{H}^+] = 10^{-\text{pH}} = 10^{-4} \, \text{mol/l}
\]
The concentration of hydrogen ions is $10^{-4}$ mol/l, which corresponds to $10^{-4}$ g/l when considering the molar mass of hydrogen ions. Since the pH is less than 7, the solution is acidic.
Therefore, the concentration of hydrogen ions is $10^{-4}$ g/l, and the solution is acidic.