Question:

Two solutions of X and Y electrolytes are taken in two beakers and diluted by adding 500 mL of water. $\Lambda_{m}$ of X increases by 1.5 times while that of Y increases by 20 times, what could be the electrolytes X and Y?

Updated On: Jul 7, 2022
  • $X \rightarrow NaCl, Y \rightarrow KCl$
  • $X \rightarrow NaCl, Y \rightarrow CH_{3}COOH$
  • $X \rightarrow KOH, Y \rightarrow NaOH$
  • $X \rightarrow CH_{3}COOH, Y \rightarrow NaCl$
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The Correct Option is B

Solution and Explanation

Electrolyte X is strong electrolyte as on dilution the number of ions remains same, only interionic attraction decreases and hence not much increase in $\wedge_{m}$ is seen. While Y is a weak electrolyte since, $\wedge_{m}$ for a weak electrolyte like$ CH_{3}COOH$ increases significantly on dilution.
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Concepts Used:

Conductance

What is conductance?

Conductance is an expression of the ease with which electric current flows through materials like metals and nonmetals. In equations, an uppercase letter G symbolizes conductance. The standard unit of conductance is siemens (S), formerly known as mho.

What is conductance in electricity?

Conductance in electricity is considered the opposite of resistance (R). Resistance is essentially the amount of friction a component presents to the flow of current.

The conductivity of electrolytic solutions is governed by the following factors:

  • Interionic attraction
  • Solvation of ions
  • The viscosity of the solvent
  • Temperature