Question:

Two drops of equal radius coalesce to form a bigger drop. What is ratio of surface energy of bigger drop to smaller one ?

Updated On: Aug 17, 2024
  • $ 2^{1/2} : 1 $
  • $ 1 :1 $
  • $ 2^{2/3} : 1 $
  • None of these
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The Correct Option is C

Solution and Explanation

Volume remains constant after coalescing. Thus,
$\frac{4}{3} \pi R^{3}=2 \times \frac{4}{3} \pi r^{3}$
where $R$ is radius of bigger drop and $r$ is radius of each smaller drop
$\therefore R=2^{1 / 3} r$
Now, surface energy per unit surface area is the surface tension. So, Surface energy, $W=T \Delta \,A$
or $W=4 \pi R^{2} T$
Therefore, surface energy of bigger drop
$ W_{1} =4 \pi\left(2^{1 / 3} r\right)^{2} T $
$=\left(2^{2 / 3}\right) 4 \pi r^{2} T$
Surface energy of smaller drop
$W_{2}=4 \pi r^{2} T$
Hence, required ratio
$\frac{W_{1}}{W_{2}}=2^{2 / 3}: 1$
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Concepts Used:

Surface Tension

The amount of energy required to increase the liquid's surface area by one unit area is known as surface tension. In other words, it is a property of the liquid surface to resist force.

Surface tension is defined as,

The ratio of the surface force F to the length L along which the force acts.

Mathematically, the surface tension formula can be expressed as follows:

T=F/L

Where,

  • F is the force per unit length
  • L is the length in which force act
  • T is the surface tension of the liquid

Read More: Detergents and Surface Tension

Factors affecting surface tension:

  • Impurities: The surface tension decreases with the addition of impurities.
  • Surfactants: Adding surfactants in liquids lowers the tension of water making it interrupt aside or get susceptible.
  • Temperature: The surface tension of a liquid reduces as the temperature rises.

The Unit of Surface Tension:

The SI unit of Surface Tension is Newton per Meter or N/m.