If the function \(f(x)=\begin{cases}(1+|\cos x|) \frac{\lambda}{|\cos x|} & , 0 < x < \frac{\pi}{2} \\\mu & , \quad x=\frac{\pi}{2} \\\frac{\cot 6 x}{e^{\cot 4 x}} & \frac{\pi}{2}< x< \pi\end{cases}\)is continuous at \(x=\frac{\pi}{2}, then 9 \lambda+6 \log _{ e } \mu+\mu^6- e ^{6 \lambda}\) is equal to
(a) State the following:
(i) Kohlrausch law of independent migration of ions
A solution of glucose (molar mass = 180 g mol\(^{-1}\)) in water has a boiling point of 100.20°C. Calculate the freezing point of the same solution. Molal constants for water \(K_f\) and \(K_b\) are 1.86 K kg mol\(^{-1}\) and 0.512 K kg mol\(^{-1}\) respectively.
Write the reactions involved when D-glucose is treated with the following reagents: (a) HCN (b) Br\(_2\) water
Identify A and B in each of the following reaction sequence:
(a) \[ CH_3CH_2Cl \xrightarrow{NaCN} A \xrightarrow{H_2/Ni} B \]
(b) \[ C_6H_5NH_2 \xrightarrow{NaNO_2/HCl} A \xrightarrow{C_6H_5NH_2} B \]
Would you expect benzaldehyde to be more reactive or less reactive in nucleophilic addition reactions than propanal? Justify your answer.