Question:

The true statement for the acids of phosphorus, $H_3PO_2$, $H_3PO_3$ and $H_3PO_4$ is

Updated On: Jul 27, 2022
  • the order of their acidity is $H_3PO_4 > H_3PO_3 > H_3PO_2$
  • all of them are reducing in nature
  • all of them are tribasic acids
  • the geometry of phosphorus is tetrahedral in all the three
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The Correct Option is D

Solution and Explanation

$H_3PO_2, H_3PO_3$ and $H_3PO_4$ contain one, two and three ionisable hydrogen atoms respectively. $ {H3PO2 <=> H+ + H2PO2^-}$ $ {H3PO3 <=> H+ + H2PO3^-}$$ { <=> H+ + HPO3^{2-}}$ $ {H3PO4 <=> H+ + H2PO4^-}$$ { <=> H+ + HPO4^{2-}}$ $ { <=> H+ + PO4^{3-}}$ But there is very little difference in acidity. As P is $sp^3$ hybridised in all therefore all are tetrahedral.
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Concepts Used:

P-Block Elements

  • P block elements are those in which the last electron enters any of the three p-orbitals of their respective shells. Since a p-subshell has three degenerate p-orbitals each of which can accommodate two electrons, therefore in all there are six groups of p-block elements.
  • P block elements are shiny and usually a good conductor of electricity and heat as they have a tendency to lose an electron. You will find some amazing properties of elements in a P-block element like gallium. It’s a metal that can melt in the palm of your hand. Silicon is also one of the most important metalloids of the p-block group as it is an important component of glass.

P block elements consist of: