Pyrophosphoric acid (\( {H}_4{P}_2{O}_7 \)) consists of two phosphoric acid molecules linked by an oxygen atom. Each phosphoric acid molecule has three \( {P} - {OH} \) bonds, and there is one additional \( {P} - {OH} \) bond between the two phosphoric acid units.
Therefore, the total number of \( {P} - {OH} \) bonds in pyrophosphoric acid is 4.
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