Question:

The Sum of number of lone pairs in central atom in IF5 and IF7 is:

Updated On: Aug 3, 2024
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In IF5 (iodine pentafluoride), the central atom is iodine (I).
Iodine has 7 valence electrons (group 7 or 17), and each fluorine (F) atom has 7 valence electrons. Therefore, the total number of valence electrons in IF5 is:
1(I) x 7 valence electrons + 5(F) x 7 valence electrons = 42 valence electrons
To determine the number of lone pairs on the central atom, we need to subtract the number of electrons involved in bonding from the total number of valence electrons.
In IF5, each fluorine atom contributes 1 electron to form a single bond with the iodine atom. Therefore, there are 5 bonding pairs (I-F) in the molecule, accounting for a total of 10 electrons.
The remaining 32 valence electrons are used to complete the octet of each fluorine atom, leaving 2 electrons on iodine. Since each lone pair has 2 electrons, there is 1 lone pair on the central atom in IF5.
In IF7 (iodine heptafluoride), the central atom is also iodine (I).
Iodine has 7 valence electrons, and each fluorine atom has 7 valence electrons. Therefore, the total number of valence electrons in IF7 is:
1(I) x 7 valence electrons + 7(F) x 7 valence electrons = 56 valence electrons
In IF7, each fluorine atom contributes 1 electron to form a single bond with the iodine atom. Therefore, there are 7 bonding pairs (I-F) in the molecule, accounting for a total of 14 electrons.
The remaining 42 valence electrons are used to complete the octet of each fluorine atom, leaving no electrons on iodine. Since there are no lone pairs on the central atom in IF7, the sum of the number of lone pairs in IF5 and IF7 is 1 + 0 = 1.
Answer. 1
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The correct answer is 0.1.00

lone pairs in central atom

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Concepts Used:

D and F Block Elements

The d-block elements are placed in groups 3-12 and F-block elements with 4f and 5f orbital filled progressively. The general electronic configuration of d block elements and f- block elements are (n-1) d 1-10 ns 1-2 and (n-2) f 1-14 (n-1) d1 ns2 respectively. They are commonly known as transition elements because they exhibit multiple oxidation states because of the d-d transition which is possible by the availability of vacant d orbitals in these elements. 

They have variable Oxidation States as well as are good catalysts because they provide a large surface area for the absorption of reaction. They show variable oxidation states to form intermediate with reactants easily. They are mostly lanthanoids and show lanthanoid contraction. Since differentiating electrons enter in an anti-penultimate f subshell. Therefore, these elements are also called inner transition elements.

Read More: The d and f block elements