The energy band gap of a semiconductor determines the range of light frequencies it can emit. For visible light emission, which falls in the approximate wavelength range of \( 400 \, \text{nm} \) to \( 700 \, \text{nm} \), the energy must coincide with the visible spectrum's energy range.
The relation between the energy of light \((E)\) in electron volts and the wavelength \((\lambda)\) in nanometers is given by:
\( E = \frac{hc}{\lambda} \)
Where:
Considering the visible light spectrum, compute the energy for the minimum wavelength (400 nm) to determine the minimum band gap for visible light emission:
\( E = \frac{(4.135667 \times 10^{-15} \, \text{eV} \cdot \text{s})(3 \times 10^8 \, \text{m/s})}{400 \times 10^{-9} \, \text{m}} \approx 3.1 \, \text{eV} \)
Considering the maximum wavelength (700 nm):
\( E = \frac{(4.135667 \times 10^{-15} \, \text{eV} \cdot \text{s})(3 \times 10^8 \, \text{m/s})}{700 \times 10^{-9} \, \text{m}} \approx 1.77 \, \text{eV} \)
Thus, a semiconductor must have at least a band gap of approximately \( 1.77 \, \text{eV} \) to emit visible light. Therefore, among the options given, the semiconductor must have at least a band gap of \( 1.8 \, \text{eV} \) to fabricate visible LEDs.