The reaction is called :
- Etard reaction
- Gatterman - Koch reaction
- Williamson synthesis
- Williamson continuous etherification process
The Correct Option is C
Solution and Explanation
Top Questions on Ethers
- Replacement of a hydrogen atom in a hydrocarbon by an alkoxy or carboxyl group yields a class of compounds known as ethers. Ethers are classified as symmetrical or unsymmetrical on the basis of groups attached to the oxygen atoms. Diethyl ether, a symmetrical ether, has been widely used as an inhalation anesthetic. Ethers can be prepared by acid catalyzed intermolecular dehydration of alcohols and Williamson's synthesis. Acid catalyzed dehydration of alcohols is not generally preferred as it gives a mixture of elimination and substitution products. In Williamson's synthesis, an alkyl halide is allowed to react with sodium alkoxide. Ethers containing substituted Alkyl groups may also be prepared by this method. The C-O bond in ether is weakly polar and is cleaved under drastic conditions with excess of hydrogen halides. In electrophilic substitution, the alkoxy group deactivates the aromatic ring and directs the incoming group to ortho and para positions.
- What happens when C₆H₅–O–R is treated with HX?
- Which of the following reagents is required for the conversion of Benzene to methyl benzoate?
(A) Br\(_2\)/FeBr\(_3\)
(B) Mg, dry Ether
(C) CO\(_2\), H\(_3\)O\(^+\)
(D) Methanol, Conc. H\(_2\)SO\(_4\) - Williamson’s synthesis of preparing dimethyl ether is a/an:
- Identify the dimethyl ether.
Questions Asked in NEET exam
Given below are two statements: One is labelled as Assertion (A) and the other is labelled as Reason (R).
Assertion (A): A typical unfertilized, angiosperm embryo sac at maturity is 8-nucleate and 7-celled.
Reason (R): The egg apparatus has 2 polar nuclei.In the light of the above statements, choose the correct answer from the options given below:
- NEET (UG) - 2025
- Angiosperms
- A ball of mass 0.5 kg is dropped from a height of 10 m. The ball hits the ground and rises to a height of 1.5 m. The impulse imparted to the ball during its collision with the ground is : (Take \(g = 9.8 \, \text{m/s}^2\))
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- Collision and Impulse
- Consider the diameter of a spherical object being measured with the help of a Vernier Callipers. Suppose its 10 Vernier Scale Divisions (V.S.D.) are equal to its 9 Main Scale Divisions (M.S.D.). The least count in the M.S. is 0.1 cm and the zero of V.S. is at -0.1 cm when the jaws of Vernier callipers are closed. If the main scale reading for the diameter is \(M = 5\) cm and the number of coinciding vernier division is 8, the measured diameter after zero error correction, is:
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- Measurement of length
- A container has two chambers of volumes \(V_1 = 2\) litres and \(V_2 = 3\) litres separated by a partition made of a thermal insulator. The chambers contain \(n_1 = 2\) moles and \(n_2 = 3\) moles of ideal gas at pressures \(p_1 = 1\) atm and \(p_2 = 2\) atm, respectively. When the partition is removed, the mixture attains an equilibrium pressure of :
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- Ideal Gases
A sphere of radius R is cut from a larger solid sphere of radius 2R as shown in the figure. The ratio of the moment of inertia of the smaller sphere to that of the rest part of the sphere about the Y-axis is :
- NEET (UG) - 2025
- Moment Of Inertia
Concepts Used:
Ethers
A class of organic compounds that mostly contain an ether group in which the oxygen atom is bonded to two alkyl or aryl groups are referred to as Ethers. For the same, C-O-C is the functional group.
Chemical Properties of Ether:
Ethers are less polar as well as less reactive, and they do not react with active metals (Na, K), cold dilute acid, oxidizing and reducing agents or other chemicals.
The reason is that they do not have an active functional group.
- Because of the presence of a lone pair on the oxygen atom, ether has a basic nature and behaves like a Lewis base. Formation of oxonium ion occurs when ethers react with cold conc. acid. Ethers, such as BF3, AICI3, and RMgX, form a dative bond with Lewis acid.
- There is a significant difference between the boiling points of ethanol and dimethyl ether. Ethanol has very much higher boiling point of 78 degrees Celsius, whereas dimethyl ether has a negative 25 degrees boiling point. And this explains the molecules' state of matter.
- Ethanol is, of course, a liquid at room temperature and pressure because its boiling point is higher than room temperature. On the other hand, Dimethyl ether already has turned into a gas due to its much lower boiling point.