Step 1: Relationship Between Centripetal Acceleration and Orbit Radius
For an electron in a hydrogen atom, the centripetal acceleration in the \( n \)th orbit is given by:
\[
a_c \propto \frac{1}{r^3}
\]
Given that the ratio of centripetal accelerations is:
\[
\frac{a_{c1}}{a_{c2}} = \frac{81}{16}
\]
Using the inverse cubic relation:
\[
\left(\frac{r_2}{r_1}\right)^3 = \frac{16}{81}
\]
Taking the cube root on both sides:
\[
\frac{r_2}{r_1} = \frac{2}{3}
\]
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Step 2: Relationship Between Radius and Angular Momentum
From Bohr's quantization rule:
\[
r_n \propto n^2
\]
So, we equate:
\[
\frac{n_2^2}{n_1^2} = \frac{r_2}{r_1} = \frac{2}{3}
\]
Taking square root:
\[
\frac{n_2}{n_1} = \sqrt{\frac{2}{3}}
\]
Since \( n \) represents the principal quantum number, considering the closest integer values, we take:
\[
n_1 = 3, \quad n_2 = 2
\]
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Step 3: Change in Angular Momentum
The angular momentum in the \( n \)th orbit is given by:
\[
L_n = n \frac{h}{2\pi}
\]
The change in angular momentum during transition is:
\[
\Delta L = L_1 - L_2 = \left(3 \frac{h}{2\pi}\right) - \left(2 \frac{h}{2\pi}\right)
\]
\[
\Delta L = \frac{h}{2\pi}
\]
Thus, the correct answer is:
\[
\mathbf{\frac{h}{2\pi}}
\]
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