The rate constant of a reaction depends on
- temperature
- initial concentration of the reactants
- time of reaction
- extent of reaction
The Correct Option is A
Solution and Explanation
$k=Ae^{E_a/RT}$
where, A = pre-exponential factor, $E_a$ = activation energy.
Top Questions on Chemical Kinetics
For the reaction \( A + B \to C \), the rate law is found to be \( \text{rate} = k[A]^2[B] \). If the concentration of \( A \) is doubled and \( B \) is halved, by what factor does the rate change?
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Questions Asked in JEE Advanced exam
As shown in the figures, a uniform rod $ OO' $ of length $ l $ is hinged at the point $ O $ and held in place vertically between two walls using two massless springs of the same spring constant. The springs are connected at the midpoint and at the top-end $ (O') $ of the rod, as shown in Fig. 1, and the rod is made to oscillate by a small angular displacement. The frequency of oscillation of the rod is $ f_1 $. On the other hand, if both the springs are connected at the midpoint of the rod, as shown in Fig. 2, and the rod is made to oscillate by a small angular displacement, then the frequency of oscillation is $ f_2 $. Ignoring gravity and assuming motion only in the plane of the diagram, the value of $\frac{f_1}{f_2}$ is:
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The reaction sequence given below is carried out with 16 moles of X. The yield of the major product in each step is given below the product in parentheses. The amount (in grams) of S produced is ____.
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Let $ a_0, a_1, ..., a_{23} $ be real numbers such that $$ \left(1 + \frac{2}{5}x \right)^{23} = \sum_{i=0}^{23} a_i x^i $$ for every real number $ x $. Let $ a_r $ be the largest among the numbers $ a_j $ for $ 0 \leq j \leq 23 $. Then the value of $ r $ is ________.
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Let $ \mathbb{R} $ denote the set of all real numbers. Then the area of the region $$ \left\{ (x, y) \in \mathbb{R} \times \mathbb{R} : x > 0, y > \frac{1}{x},\ 5x - 4y - 1 > 0,\ 4x + 4y - 17 < 0 \right\} $$ is
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Concepts Used:
Chemical Kinetics
Chemical kinetics is the description of the rate of a chemical reaction. This is the rate at which the reactants are transformed into products. This may take place by abiotic or by biological systems, such as microbial metabolism.
Rate of a Chemical Reaction:
The speed of a reaction or the rate of a reaction can be defined as the change in concentration of a reactant or product in unit time. To be more specific, it can be expressed in terms of: (i) the rate of decrease in the concentration of any one of the reactants, or (ii) the rate of increase in concentration of any one of the products. Consider a hypothetical reaction, assuming that the volume of the system remains constant. R → P
Read More: Chemical Kinetics MCQ
Factors Affecting The Reaction Rate:
- The concentration of Reactants - According to collision theory, which is discussed later, reactant molecules collide with each other to form products.
- Nature of the Reactants - The reaction rate also depends on the types of substances that are reacting.
- Physical State of Reactants - The physical state of a reactant whether it is solid, liquid, or gas can greatly affect the rate of change.
- Surface Area of Reactants - When two or more reactants are in the same phase of fluid, their particles collide more often than when either or both are in the solid phase or when they are in a heterogeneous mixture. In a heterogeneous medium, the collision between the particles occurs at an interface between phases. Compared to the homogeneous case, the number of collisions between reactants per unit time is significantly reduced, and so is the reaction rate.
- Temperature - If the temperature is increased, the number of collisions between reactant molecules per second. Increases, thereby increasing the rate of the reaction.
- Effect Of Solvent - The nature of the solvent also depends on the reaction rate of the solute particles.
- Catalyst - Catalysts alter the rate of the reaction by changing the reaction mechanism.