Step 1: The rate law for a chemical reaction is given by \[ {rate} = k[A]^n \] where \(k\) is the rate constant, \([A]\) is the concentration of the reactant, and \(n\) is the order of the reaction.
For the rate and rate constant to have the same units, the order of the reaction must be zero.
This is because, in a zero-order reaction, the rate is constant and does not depend on the concentration of the reactant.
Therefore, the unit of the rate constant is equal to the unit of rate.
In the Carius method of estimation of halogen, 0.4g of an organic compound gave 0.188g of AgBr. What is the percentage of bromine in the organic compound? (The atomic mass of Ag = 108 g mol\(^{-1}\) & Br = 80 g mol\(^{-1}\))
For the reaction:
\[ 2A + B \rightarrow 2C + D \]
The following kinetic data were obtained for three different experiments performed at the same temperature:
\[ \begin{array}{|c|c|c|c|} \hline \text{Experiment} & [A]_0 \, (\text{M}) & [B]_0 \, (\text{M}) & \text{Initial rate} \, (\text{M/s}) \\ \hline I & 0.10 & 0.10 & 0.10 \\ II & 0.20 & 0.10 & 0.40 \\ III & 0.20 & 0.20 & 0.40 \\ \hline \end{array} \]
The total order and order in [B] for the reaction are respectively: