Vulcanization is a chemical process where rubber is heated with sulfur. This process:
• Forms cross-links between polymer chains of rubber molecules through disulfide bridges between the double bonds present in natural rubber.
• Increases elasticity: These cross-links make the rubber more elastic by reducing the movement of polymer chains.
• Increases hardness: It also makes it harder and more durable as it also increases the tensile strength.
• Reduced solubility It makes it less soluble in solvents.
Therefore, vulcanization makes the rubber more elastic and hard.
The product (P) formed in the following reaction is: