Step 1: Understand the O–H bond length in water.
The bond length between oxygen and hydrogen atoms in a water molecule depends on the phase (gas or liquid) due to intermolecular interactions.
Step 2: Bond length in gas phase.
- In the gas phase, water molecules are isolated with minimal intermolecular forces.
- This results in a shorter O–H bond length compared to the liquid phase.
- Experimental measurements show that the O–H bond length in gaseous water is approximately 95.7 pm.
Step 3: Conclusion.
Therefore, the O–H bond length in water vapor (gas phase) is 95.7 pm.