Question:

The number of unpaired electrons in the complex ion \([CoF_6]^{3–}\) is: (Atomic No.of Co = 27) 

Updated On: Oct 17, 2023
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The Correct Option is C

Solution and Explanation

Cobalt has an atomic number of 27. The electron configuration for a neutral cobalt atom (Co) is: 1s2 2s2 2p6 3s2 3p6 4s2 3d7
When cobalt forms the complex \([CoF_6]^{3-}\), it loses three electrons to become \(Co^{3+}\): 1s2 2s2 2p6 3s2 3p6 4s0 3d6
Now, you can count the number of unpaired electrons in the 3d orbitals. In this case, there are 4 unpaired electrons. 

So, the correct answer is (C) : 4

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Concepts Used:

Coordination Compounds

A coordination compound holds a central metal atom or ion surrounded by various oppositely charged ions or neutral molecules. These molecules or ions are re-bonded to the metal atom or ion by a coordinate bond.

Coordination entity:

A coordination entity composes of a central metal atom or ion bonded to a fixed number of ions or molecules.

Ligands:

A molecule, ion, or group which is bonded to the metal atom or ion in a complex or coordination compound by a coordinate bond is commonly called a ligand. It may be either neutral, positively, or negatively charged.