To determine the number of six-membered and five-membered rings in Buckminsterfullerene (C60), we need to understand its structure. Buckminsterfullerene is a fullerene molecule with a truncated icosahedron shape, resembling a soccer ball. It consists of 60 carbon atoms arranged in a combination of pentagonal and hexagonal rings.
1. Structure of Buckminsterfullerene:
- Buckminsterfullerene (C60) has a total of 32 faces, with each face being a ring of carbon atoms.
- These faces are composed of pentagons (5-membered rings) and hexagons (6-membered rings).
- Each carbon atom is shared among three rings, and each edge is shared between two rings.
2. Counting the Rings:
- It is a well-established fact in chemistry that C60 has 12 pentagonal rings and 20 hexagonal rings.
- This can be derived using Euler's formula for polyhedra, $ V - E + F = 2 $, where:
- $ V $ is the number of vertices (60 carbon atoms),
- $ E $ is the number of edges (90, since each vertex has degree 3, so $ 3V/2 = 3 \cdot 60 / 2 = 90 $),
- $ F $ is the number of faces (32, including both pentagons and hexagons).
- Let $ P $ be the number of pentagonal faces and $ H $ be the number of hexagonal faces. Then:
- $ P + H = 32 $ (total faces).
- Each pentagon has 5 edges, and each hexagon has 6 edges, but since each edge is shared between two faces, the total number of edges is given by:
$ \frac{5P + 6H}{2} = 90 \implies 5P + 6H = 180 $.
- Additionally, for a fullerene to be stable, it typically has exactly 12 pentagons (a property of closed carbon cages). So, $ P = 12 $.
- Substituting $ P = 12 $ into $ P + H = 32 $:
$ 12 + H = 32 \implies H = 20 $.
- Verify with the edge equation:
$ 5 \cdot 12 + 6 \cdot 20 = 60 + 120 = 180 \implies \frac{180}{2} = 90 $ edges, which is correct.
3. Conclusion:
- Buckminsterfullerene has 12 five-membered rings (pentagons) and 20 six-membered rings (hexagons).
Answer: The correct option is (A) 12, 20.
1. Understanding the Structure of Buckminster Fullerene:
Buckminster Fullerene (C₆₀) is a molecule made up of 60 carbon atoms arranged in a spherical shape. It consists of 12 pentagonal (five-membered) rings and 20 hexagonal (six-membered) rings, forming a structure similar to a soccer ball, also known as a truncated icosahedron.
2. Identifying the Number of Rings:
In Buckminster Fullerene, the structure is composed of 12 pentagonal rings and 20 hexagonal rings. This arrangement is fixed and unique to the C₆₀ molecule.
Final Answer:
The number of six-membered and five-membered rings in Buckminster Fullerene is (A) 12, 20.
Consider the following compound (X):
The most stable and least stable carbon radicals, respectively, produced by homolytic cleavage of corresponding C - H bond are: