Question:

The number of molecules which gives haloform test among the following molecules is
Molecules

Show Hint

The halform test is used to identify compounds containing a methyl ketone group (\( -COCH_3 \)) or a similar structure.
Updated On: Mar 21, 2025
Hide Solution
collegedunia
Verified By Collegedunia

Correct Answer: 3

Approach Solution - 1

Molecules having
Molecules
gives positive haloform test.
So , 
Molecules giving haloform
gives haloform test
So, the correct answer is 3.

Was this answer helpful?
0
3
Hide Solution
collegedunia
Verified By Collegedunia

Approach Solution -2

The halform test is positive for compounds that contain a methyl group directly attached to a carbonyl group (i.e., the \( \text{CH}_3\text{-CO-} \) functional group) or other reactive groups like \( \text{CH}_3\text{-CO-H} \).

Looking at the structures:

  • The molecules \( \text{C} = \text{O} - \text{CH}_3 \) and \( \text{OH} - \text{C} - \text{CH}_3 \) give a positive halform test because they both have the required functional groups for the reaction.
  • The other molecules do not meet the criteria.

Thus, the number of molecules giving a positive halform test is 3.

Was this answer helpful?
0
0

Top Questions on Chemical Reactions of Aldehydes Ketones and Carboxylic Acids

View More Questions

Concepts Used:

Aldehydes, Ketones, and Carboxylic Acids

Aldehydes, Ketones, and Carboxylic Acids are carbonyl compounds that contain a carbon-oxygen double bond. These organic compounds are very important in the field of organic chemistry and also have many industrial applications.

Aldehydes:

Aldehydes are organic compounds that have the functional group -CHO.

Preparation of Aldehydes

Acid chlorides are reduced to aldehydes with hydrogen in the presence of palladium catalyst spread on barium sulfate.

Ketones:

Ketones are organic compounds that have the functional group C=O and the structure R-(C=O)-R’.

Preparation of Ketones

Acid chlorides on reaction with dialkyl cadmium produce ketones. Dialkyl cadmium themselves are prepared from Grignard reagents.

Carboxylic Acid:

Carboxylic acids are organic compounds that contain a (C=O)OH group attached to an R group (where R refers to the remaining part of the molecule).

Preparation of Carboxylic Acids

Primary alcohols are readily oxidized to carboxylic acids with common oxidizing agents such as potassium permanganate in neutral acidic or alkaline media or by potassium dichromate and chromium trioxide in acidic media.