The correct answer is 5
The orbitals \( p_{x}, p_{y}, p_{z}, d_{z^{2}}, \) and \( d_{x^{2}-y^{2}} \) are considered axial orbitals. The \( p \)-orbitals, such as \( p_{x}, p_{y}, \) and \( p_{z} \), have their lobes aligned along the x, y, and z axes, respectively.
These are termed as axial orbitals since they lie along the axis of symmetry of a molecule. The \( d \)-orbitals, specifically \( d_{z^{2}} \) and \( d_{x^{2}-y^{2}} \), also align with the axis of symmetry and are part of the axial set, which directly participate in bonding along the principal axis in a molecule.
Which of the following statement is true with respect to H\(_2\)O, NH\(_3\) and CH\(_4\)?
(A) The central atoms of all the molecules are sp\(^3\) hybridized.
(B) The H–O–H, H–N–H and H–C–H angles in the above molecules are 104.5°, 107.5° and 109.5° respectively.
(C) The increasing order of dipole moment is CH\(_4\)<NH\(_3\)<H\(_2\)O.
(D) Both H\(_2\)O and NH\(_3\) are Lewis acids and CH\(_4\) is a Lewis base.
(E) A solution of NH\(_3\) in H\(_2\)O is basic. In this solution NH\(_3\) and H\(_2\)O act as Lowry-Bronsted acid and base respectively.
Which of the following linear combinations of atomic orbitals will lead to the formation of molecular orbitals in homonuclear diatomic molecules (internuclear axis in z-direction)?
(1) \( 2p_z \) and \( 2p_x \)
(2) \( 2s \) and \( 2p_x \)
(3) \( 3d_{xy} \) and \( 3d_{x^2-y^2} \)
(4) \( 2s \) and \( 2p_z \)
(5) \( 2p_z \) and \( 3d_{x^2-y^2} \)
A bob of mass \(m\) is suspended at a point \(O\) by a light string of length \(l\) and left to perform vertical motion (circular) as shown in the figure. Initially, by applying horizontal velocity \(v_0\) at the point ‘A’, the string becomes slack when the bob reaches at the point ‘D’. The ratio of the kinetic energy of the bob at the points B and C is: 
The Molecular Orbital Theory is a more sophisticated model of chemical bonding where new molecular orbitals are generated using a mathematical process called Linear Combination of Atomic Orbitals (LCAO).
Molecular Orbital theory is a chemical bonding theory that states that individual atoms combine together to form molecular orbitals. Due to this arrangement in MOT Theory, electrons associated with different nuclei can be found in different atomic orbitals. In molecular orbital theory, the electrons present in a molecule are not assigned to individual chemical bonds between the atoms. Rather, they are treated as moving under the influence of the atomic nuclei in the entire molecule.
