Question:

The most suitable method of the separation of a mixture of ortho and para nitrophenol mixed in the ratio of 1 : 1 is

Updated On: Jul 13, 2024
  • distillation
  • crystallisation
  • vaporisation
  • colour spectrum
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The Correct Option is A

Solution and Explanation

In ortho and para-nitrophenol, ortho-nitrophenol has intramolecular H-bonding. So, it has lower boiling point. Intermolecular H-bonding more strong then intramolecular H-bonding. Whereas para-nitrophenol has intermolecular H-bonding. So, it has higher boiling point. Due to difference in boiling points ortho and para-nitrophenol can be separated from each other by distillation.
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