Step 1: Expansive Clay Minerals.
The most expansive clay mineral is Montmorillonite. This mineral has a high ability to swell when exposed to water, making it the most expansive type of clay.
Step 2: Conclusion.
Thus, the correct answer is Montmorillonite, making option (2) the correct answer.
Final Answer:
\[
\boxed{2. \, \text{Montmorillonite}}
\]