Buna-S, also known as styrene-butadiene rubber, is a synthetic polymer produced through the copolymerization of:
\[
\text{Butadiene (CH}_2\text{=CH-CH=CH}_2\text{)} \quad \text{and} \quad \text{Styrene (C}_6\text{H}_5\text{-CH=CH}_2\text{)}.
\]
This process follows a 3:1 ratio of butadiene to styrene. Buna-S is commonly used in the production of automobile tires because of its high durability and resistance to wear.
Other options:
- Isoprene is the primary monomer used in natural rubber.
- Phenol and vinyl chloride do not form part of Buna-S's composition.
Final Answer:
\[
\boxed{\text{Styrene and butadiene}}
\]