Question:

The maximum number of $90^\circ$ angles between bond pair-bond pair of electrons is observed in

Updated On: Jul 27, 2022
  • $dsp^3$ -hybridisation
  • $sp^3d^2$-hybridisation
  • $dip^2$-hybridisation
  • $sp^3$ d-hybridisation
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The Correct Option is B

Solution and Explanation

$sp ^{3} d ^{2}$ hybridisation confirms to octahedral or square bipyramidal configuration. Square Pyramidal. This molecule is made up of 6 equally spaced $sp ^{3} d ^{2}$ hybrid orbitals arranged at $90^{\circ}$ angles. The shape of the orbitals is octahedral. One orbital contains a lone pair of electrons so the remaining five atoms connected to the central atom give the molecule a square pyramidal shape.
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Concepts Used:

Chemical Bonding and Molecular Structure

Such a group of atoms is called a molecule. Obviously, there must be some force that holds these constituent atoms together in the molecules. The attractive force which holds various constituents (atoms, ions, etc.) together in different chemical species is called a chemical bond.

Types of Chemical Bonds:

There are 4 types of chemical bonds which are formed by atoms or molecules to yield compounds. 

  • Ionic Bonds - Ionic bonding is a type of chemical bonding which involves a transfer of electrons from one atom or molecule to another.
  • Covalent Bonds - Compounds that contain carbon commonly exhibit this type of chemical bonding. 
  • Hydrogen Bonds -  It is a type of polar covalent bonding between oxygen and hydrogen wherein the hydrogen develops a partial positive charge
  • Polar Bonds - In Polar Covalent chemical bonding, electrons are shared unequally since the more electronegative atom pulls the electron pair closer to itself and away from the less electronegative atom.

Factors Affecting Bond Enthalpy in Chemical Bonding:

  • Size of the Atom
  • Multiplicity of Bonds
  • Number of Lone Pair of Electrons Present
  • Bond Angle